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Kim Possible looks like an average high-school cheerleader, but in her spare time, she saves the world from super-villains. Watch full episodes here on Disney LOL. Kim Possible: The Villain Files (2004) Watch Kim Possible: The Villain Files (2004) full movie online. Synopsis: The world’s coolest teen crime fighter is at it again as she and her trusted sidekick Ron Stoppable keep the world safe from more seriously wacko bad guys in KIM POSSIBLE: THE VILLAIN FILES.